Re: Battery Rejuve???

Gerald O'Docharty ( (no email) )
Tue, 14 Apr 1998 19:57:02 -0400

The sulfation that kills lead acid batteries is a hard cystalline form
of the lead sulfate. Each time you discharge the battery the lead
suflate forms in a soft easily broken down form. If it sits for a long
time in the discharged or partially discharged state, the sulfate
hardens as large crystals begin to form. The crystals are resistant to
dissolution by the charging current but higher voltage can help.
Periodically over-charging a battery can help knock off some of the
smaller crystals. This is called 'equalization'. The battery is
overcharged to a good boil for a short time. Then the water is
replenished as needed. Just don't let it get below the plates. It is the
reduced effective plate area that eventually renders the battery useless
when sulfation covers the plates. It acts as an insulator.

Some of the new pulse charging techniques rely on resonating the sulfate
bond at its resonant frequancy to break up the crystals. This allows the
sulfate ions to return to solution and be recycled rather that settling
to the bottom of the cells.

There is a chemical that has the ability to restore some life to lead
acid batteries by chemically stripping some of the sulfation. It is
called EDTA (ethylenediamine tetraacetic acid) a relative of vinegar. It
leaves it as a precipitate which settles to the bottom of the battery.
It still will not remove hard sulfate crystals from a long dead battery.
Eventually any lead acid battery will die of old age when the plates and
straps are eroded away from repeated dissolution and redeposition but
this is mechanical.
-Gerald O'

> Yes, I didn't mention that one...called the guy about a month ago but no
> answer...I still think its the best way. Also talked to the inventor
> out in Phoenix....he's a neat guy and continues making improved
> prototypes. He said he got the idea from a Pop Sci article about
> battery chargers that used square waves and seemed to be more efficient.
>
> Hadn't seen this chemical thing before. I didn't see anything in their
> literature saying how many times you could do this before the battery
> was no longer reclaimable.