|
255Fm(20.1hr)
256Lr(28s)
260Ha(1.5s)
263Sg(0.8s)
266Mt(3.4ms)
The transuranium elements have atomic numbers higher than uranium (#92). Twenty
of these elements have been discovered; all are unstable with half-lives (time
needed for half the sample to decay) ranging millions of years to mere
fractions of a second. Two of the twenty have been found in nature (neptunium
and plutonium) but only in trace amounts. Transuranium elements are produced
artificially by bombarding heavy atoms either with neutrons produced in nuclear
reactors or with charged particles accelerated to high energy.
In 1940 the first transuranium element was produced when McMillan & Abelson at
Berkeley exposed uranium oxide to neutrons from a cyclotron. The resulting
product was named neptunium (#93). The discovery of the next transuranium
element was in 1940 by Seaborg, Kennedy & Wah and named plutonium (#94).
Seaborg predicted the following electron configurations:
104-112 add to [Rn] 5f14 |
113-121 add to [Rn] 5f14
6d10 |
104 7s2 6d2 |
113 7s2 7p1 |
105 7s2 6d3 |
114 7s2 7p2 |
106 7s2 6d4 |
115 7s2 7p3 |
107 7s2 6d5 |
116 7s2 7p4 |
108 7s2 6d6 |
117 7s2 7p5 |
109 7s2
6d7 |
118 7s2 7p6 |
110 7s2 6d8 |
119 7s2 7p1
8s1 |
111 7s2 6d9 |
120 7s2 7p1
8s2 |
112 7s2 6d10 |
121 7s2 7p1
8s2 7d1 |
Only Np, Pu, and Am have uses (very small amounts of the others have been
made).
Np: Component in neutron detection instruments
Pu: Nuclear weapons, nuclear power, pacemakers
Am: Source for smoke detectors and portable source of gamma rays
Until 1997, the International Union of Pure and Applied Chemistry (IUPAC)
recommended different names for elements 104-109 than those suggested by
American Chemical Society (ACS). IUPAC and ACS currently differ only for
elements 105 & 107.
Element # |
IUPAC until 1997 |
Current IUPAC |
ACS |
104 |
unnilquadrium |
rutherfordium (Rf) |
rutherfordium |
105 |
unnilpentium |
dubium (Db) |
hahnium (Ha) |
106 |
unnilhexium |
seaborgium (Sg) |
seaborgium |
107 |
unnilseptium |
bohrium (Bh) |
nielsbohrium (Ns) |
108 |
unniloctium |
hassium (Hs) |
hassium |
109 |
unnilennium |
meitnerium (Mt) |
meitnerium |
The transuranium elements were named after planets (neptunium & plutonium),
places (America, Berkeley, California, Nuclear Institute at Dubna Russia, &
Latin word "Hess" for German state), and scientists. Some scientists are highly
recognizable (Einstein #99) or mentioned in freshman chemistry (Bohr #107). The
remainder of this article describes the work of Fermi (#100), Lawrence (#103),
Hahn (#105), Seaborg (#106), and Meitner (#109).
Enrico Fermi (1901-1954)
In 1934, while professor of physics at the University of Rome, Fermi bombarded a
variety of elements with neutrons. He discovered that slow moving neutrons were
especially effective in producing radioactive atoms. In 1938 Fermi was awarded
the Nobel Prize in physics for identification of new radioactive elements
produced by neutron bombardment and for his discovery of nuclear reaction
effected by slow neutrons. He was given permission by the Fascist government of
Mussolini to travel to Sweden to receive the award; Fermi and his wife left
Italy never to return. Unknown to Fermi and the Nobel Prize Committee, the "new
elements" Fermi characterized weren't new but a result of splitting uranium.
Enrico Fermi settled in the United States and devised the crucial experiment on
December 2, 1942 that produced the chain reaction needed to make an atomic bomb.
During World War II he became part of the team that developed the atomic bomb
and later pioneered research using high energy particles.
Ernest Lawrence (1901-1958)
When Lawrence joined the physics faculty at Berkeley in 1928, the hottest topic
in physics was bombarding the atom's nucleus to see what new particles it might
produce. Lawrence read about a theoretical linear accelerator that was too long
to be practicle. Lawrence knew that a magnetic field would deflect the charged
particles into a curved path. By making the particles go in a spiral, he could
boost the energy bit by bit each time they circled an electrode The university
gave Lawrence approval and in 1930 the
cyclotron was born. This
new tool launched the modern era of high-energy physics. In 1961, element 103
was and named in his honor.
Otto Hahn (1879-1968)
In 1938, Otto Hahn repeated Fermi's experiments of bombarding uranium with
neutrons. Hahn and co-worker Fritz Strassmann discovered three isotopes of
barium had been produced. This was incredible because the mass of barium is
about half of uranium and no known reaction could explain such a huge change.
Hahn, a chemist, could not offer an explanation. He wrote to Lise Meitner, his
longtime collaborator, describing his findings and asking "Perhaps you can
suggest some fantastic explanation," which she explained as nuclear fission.
Nevertheless, despite the contributions of Strassmann and Meitner, it was Hahn
who was awarded the 1945 Nobel Prize in chemistry for the discovery.
Unfortunately, Hahn was not at the awards ceremony to receive his prize. At the
time he learned of the award, he was being held by the British who were seeking
information from him about the failed German effort to develop an atomic bomb.
As the chairman of the Nobel Committee for Chemistry reported "Professor Hahn
has informed us that he is regrettably unable to attend this ceremony."
Glenn Seaborg (1912-1999)
After graduating from UCLA with a degree in chemistry in 1934, Seaborg did
graduate work at Berkeley under Gilbert Lewis (acid-base theory) and completed
his Ph.D. in 1937 under Ernest Lawrence (fast neutrons). During World War II he
headed the group which devised the chemical extraction processes used in the
production of plutonium for the Manhattan Project. Besides plutonium, Seaborg
discovered americium, curium, berkelium, californium, einsteinium, fermium,
mendelevium and nobelium. In 1944 Seaborg formulated the actinide series
placing elements 90-103 at the bottom of periodic table. For discoveries of
the transuranium elements, Seaborg was awarded the 1951 Nobel Prize in chemistry.
Seaborgium, atomic number 106, represents the first time an element had been
named after a living person.
Lise Meither (1878-1968)
Meitner, first woman to receive doctorate in physics from the University of
Vienna, began work in 1907 with Otto Hahn at the University of Berlin. They
studied radioactive substances for the next 30 years; she did the physics and he
the chemistry. Together and independently they achieved important results in the
new field of nuclear physics including techniques for purifying radioactive
material, discovering the element protactinium (#91), and explaining how gamma
rays eject orbital electrons.
Leaving Germany in 1938 because of her Jewish ancestry, Meitner obtained an
appointment at the Physics Institute in Stockholm. Otto Hahn, who was still in
Germany, repeated some of Fermi's early experiments. He wrote Meitner reporting
how bombarding uranium with neutrons produced radioactive barium. Meitner,
realizing that uranium had been split, made calculations showing the formation
of barium, krypton, additional neutrons, and energy. When
Leo Szilard at Columbia
University discovered that more neutrons were produced than used in the fission,
he convinced Einstein to write President Franklin Roosevelt (see
letter) to set up program for creating Atomic Bomb. The first fission bomb
resulted from bombarding 235U with a neutron to form 236U;
236U immediately barium, krypton, 3 additional neutrons, and
enormous amount of energy. The 3 neutrons can strike three 235U
nuclei and generate 9 neutrons, which can generate 27 neutrons, and so on (chain
reaction).
235U + 0n
®
236U
® 141Ba
+ 92Kr + 3 1n
+ energy
Meitner & Hahn named the process "nuclear fission" and reported the results in
the journal Nature (1939). In 1945 the Nobel Prize in Chemistry was
awarded to Otto Hahn for the discovery of nuclear fission. Probably due to
Meitner's leaving Germany, the Nobel committee failed to understand her part in
the work. Lise Meitner was probably the most significant woman scientist of the
20th century.
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